Ergebnis für URL: http://hyperphysics.phy-astr.gsu.edu/hbase/Solids/ferro.html Ferromagnetism
Iron, nickel, cobalt and some of the rare earths (gadolinium, dysprosium) exhibit
a unique magnetic behavior which is called ferromagnetism because iron (ferrum in
Latin) is the most common and most dramatic example. Samarium and neodymium in
alloys with cobalt have been used to fabricate very strong [1]rare-earth magnets.
Ferromagnetic materials exhibit a [2]long-range ordering phenomenon at the atomic
level which causes the unpaired electron spins to line up parallel with each
other in a region called a [3]domain. Within the domain, the magnetic field is
intense, but in a bulk sample the material will usually be unmagnetized because
the many domains will themselves be randomly oriented with respect to one
another. Ferromagnetism manifests itself in the fact that a small externally
imposed [4]magnetic field, say from a [5]solenoid, can cause the magnetic domains
to line up with each other and the material is said to be magnetized. The driving
magnetic field will then be increased by a large factor which is usually
expressed as a [6]relative permeability for the material. There are many
practical [7]applications of ferromagnetic materials, such as the
[8]electromagnet.
Ferromagnets will tend to stay magnetized to some extent after being subjected to
an external magnetic field. This tendency to "remember their magnetic history" is
called [9]hysteresis. The fraction of the saturation magnetization which is
retained when the driving field is removed is called the [10]remanence of the
material, and is an important factor in permanent magnets.
All ferromagnets have a maximum temperature where the ferromagnetic property
disappears as a result of thermal agitation. This temperature is called the
[11]Curie temperature.
Ferromagntic materials will respond mechanically to an impressed magnetic field,
changing length slightly in the direction of the applied field. This property,
called [12]magnetostriction, leads to the familiar hum of transformers as they
respond mechanically to 60 Hz AC voltages.
[13]Magnetic properties of solids [14]Table of magnetic properties
[15]Table of Curie temperatures
[16]Index
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Long Range Order in Ferromagnets
The long range order which creates [21]magnetic domains in [22]ferromagnetic
materials arises from a quantum mechanical interaction at the atomic level. This
interaction is remarkable in that it locks the magnetic moments of neighboring
atoms into a rigid parallel order over a large number of atoms in spite of the
thermal agitation which tends to randomize any atomic-level order. Sizes of
domains range from a 0.1 mm to a few mm. When an external magnetic field is
applied, the domains already aligned in the direction of this field grow at the
expense of their neighbors. If all the spins were aligned in a piece of iron, the
field would be about 2.1 Tesla. A magnetic field of about 1 T can be produced in
annealed iron with an external field of about 0.0002 T, a multiplication of the
external field by a factor of 5000! For a given ferromagnetic material the long
range order abruptly disappears at a certain temperature which is called the
[23]Curie temperature for the material. The Curie temperature of iron is about
1043 K.
[24]Index
Reference
[25]Ohanian
Sec 33-3
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The Curie Temperature
For a given [30]ferromagnetic material the [31]long range order abruptly
disappears at a certain temperature which is called the Curie temperature for the
material. The Curie temperature of iron is about 1043 K. The Curie temperature
gives an idea of the amount of energy it takes to break up the long-range
ordering in the material. At 1043 K the [32]thermal energy is about 0.135 eV
compared to about 0.04 eV at room temperature.
[33]Magnetic properties of solids [34]Table of Curie temperatures
[35]Index
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Magnetic Domains
The [40]microscopic ordering of electron spins characteristic of
[41]ferromagnetic materials leads to the formation of regions of magnetic
alignment called domains.
[domain.png]
The main implication of the domains is that there is already a high degree of
magnetization in ferromagnetic materials within individual domains, but that in
the absence of external magnetic fields those domains are randomly oriented. A
modest applied magnetic field can cause a larger degree of alignment of the
magnetic moments with the external field, giving a large multiplication of the
applied field.
These illustrations of domains are conceptual only and not meant to give an
accurate scale of the size or shape of domains. The microscopic evidence about
magnetization indicates that the net magnetization of ferromagnetic materials in
response to an external magnetic field may actually occur more by the growth of
the domains parallel to the applied field at the expense of other domains rather
than the reorientation of the domains themselves as implied in the sketch.
[domains2.png]
Some of the more direct evidence we have about domains comes from imaging of
domains in single crystals of ferromagnetic materials. The sketches above are
after Young and are adapted from magnified images of domain boundaries in single
crystals of nickel. They suggest that the effect of external magnetic fields is
to cause the domain boundaries to shift in favor of those domains which are
parallel to the applied field. It is not clear how this applies to bulk magnetic
materials which are polycrystalline. Keep in mind the fact that the internal
magnetic fields which come from the [42]long range ordering of the electron spins
are much stronger, sometimes hundreds of times stronger, than the external
magnetic fields required to produce these changes in domain alignment. The
effective multiplication of the external field which can be achieved by the
alignment of the domains is often expressed in terms of the [43]relative
permeability.
Domains may be made visible with the use of magnetic colloidal suspensions which
concentrate along the domain boundaries. The domain boundaries can be imaged by
polarized light, and also with the use of electron diffraction. Observation of
domain boundary movement under the influence of applied magnetic fields has aided
in the development of theoretical treatments. It has been demonstrated that the
formation of domains minimizes the magnetic contribution to the free energy.
[44]Index
References
[45]Young
Sec 29-8
[46]Myers
Ch. 11
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Relative Permeability
The [51]magnetic constant µ[0] = 4p x 10^-7 T m/A is called the [52]permeability
of space. The permeabilities of most materials are very close to µ[0] since most
materials will be classified as either [53]paramagnetic or [54]diamagnetic. But
in [55]ferromagnetic materials the permeability may be very large and it is
convenient to characterize the materials by a relative permeability.
[relper.png]
[56]Table of magnetic properties
When ferromagnetic materials are used in applications like an [57]iron-core
solenoid, the relative permeability gives you an idea of the kind of
multiplication of the applied magnetic field that can be achieved by having the
ferromagnetic core present. So for an ordinary iron core you might expect a
magnification of about 200 compared to the magnetic field produced by the
solenoid current with just an air core. This statement has exceptions and limits,
since you do reach a saturation magnetization of the iron core quickly, as
illustrated in the discussion of [58]hysteresis.
[59]Magnetic properties of solids
[60]Index
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Applications of Ferromagnetism
[65]Electromagnets
[66]Magnetic tape recording
[67]Transformers
[68]Ferromagnetism
[69]Index
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References
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